Abstract |
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Recent years have witnessed a resurgence of novel, efficient and practical protocols for radical-mediated cross coupling reactions involving N-(acyloxy)phthalimides (NHPI esters) as redox-active esters. After the initial discovery of redox active properties of NHPI esters, an exciting range of SET-based cross coupling reactions under thermal or photolytic conditions leading to diverse C-X (X = C, B, Si, Se, S) bonds have been published. The operational simplicity and broad applicability exhibited in redox active NHPI ester based cross couplings bode well for its widespread adoption. The review presented herein covers all the recent developments in the field of redox active ester (RAE)-based cross couplings since the initial discovery. Depending on the conditions employed the reactions have been categorized in to photoinduced- and non-photoinduced cross couplings with representative examples and insightful mechanistic discussions. |
More about the article can be found here S. Murarka*, N-(acyloxy)phthalimides as Redox-Active Esters in Cross Coupling Reactions, Adv. Synth. Catal. 2018, DOI 10.1002/adsc.201701615. |
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More about the article can be found here |
S. Murarka*, N-(acyloxy)phthalimides as Redox-Active Esters in Cross Coupling Reactions, Adv. Synth. Catal. 2018, DOI 10.1002/adsc.201701615. |